VII Iberoamerican Conference on Phase equilibria for Process Design

Morelia, Michoacan (MEXICO), October 21 – 25, 2006

 

Plenary Lecture
"The Thermodynamics of Fluids in Carbon Nanotubes and other Nanoporous Media"
Stanley I. Sandler

Department of Chemical Engineering

Center for Molecular and Engineering Thermodynamics

University of Delaware, Newark, Delaware 19716, USA

Abstract

The thermodynamic properties, phase transitions and transport properties of fluid in carbon nanotubes and other nanoporous materials are very different than bulk fluids. This is a result of the highly curved nature of such materials, the interactions of the adsorbate with the surfaces, and the relative importance of adsorbate-adsorbate and adsorbate-surface interactions. In this talk the use of quantum mechanics (to obtain appropriate gas-surface interactions), simulation )to obtain both adsorption isotherms and transport properties), and then solving macrosopic transport equations to obtain fluxes will be discussed.